Arrêté - Préfecture - Mayotte - Piècecomplémentaire3 partie2 2

Documents similaires

Arrêté - Préfecture - Mayotte - Piècecomplémentaire3 partie

Arrêté - Préfecture - Mayotte - Piècecomplémentaire3 partie

Arrêté - Préfecture - Mayotte - AAP MILDECA MAYOTTE 2024 si

Arrêté - Préfecture - Mayotte - Piècecomplémentaire3 partie

Arrêté - Préfecture - Mayotte - AAP MILDECA 2023

Arrêté - Préfecture - Mayotte - Etat parcellaire.

Arrêté - Préfecture - Mayotte - Piècecomplémentaire3 partie

Arrêté - Préfecture - Mayotte - Annexe 2 relevé cadastre

Arrêté - Préfecture - Mayotte - tableau cadastres et propri

Arrêté - Préfecture - Mayotte - Arrêté n°2022 SGAR 900

Arrêté - Préfecture - Mayotte - Piècecomplémentaire3 partie2 2 Document publié le undefined NaN undefined NaN à NaNhNaN Lien du pdf (Arrêté - Préfecture - Mayotte - Piècecomplémentaire3 partie2 2)Thèmes du document : Entrepreneuriat et startup, Fiscalité, Tabac et addictions, Penetrati ade 35 ï n

Environmental précautions Prevent spill from entering municipal sewers and water sources as it may cause blockages. Advise the relevant authorities if contaminations

have occurred.

7. HANDLING AND STORAGE

Safe. handling advice

Storage Information.

Storage. and handiing

procedures

On rare occasions, Hydrogert Sulphide may be present which can

accumulate to hazardous levels in enclosed spaces, Avoid all personal

contact and breathing of gas,

Adequately vented storage tanks should be mäintained below 100°C to

prevent evolution of Hydrogen sulphide or degradation of the product.

Avold local overheating. when raising to pumping temperature.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Occupational Exposure Limits (OELs)

Components CAS-No. Source TWA Value Notations

Asphalt 8052-42-4 ACGIH TLV | LTEL 0,5 mg/m3 Fumes

LTEL: Long Term Exposure Limits - Time Weight Average (TWA) over 8 hours,

STEL: Short Term Exposure Limlts - Time Weight Average (TWA) over 15 Minutes

Note: Limits Shown for guidance only, Follow applicable regulations,

Personal Protection Equipment (PPE)

Engineering controls

Respiratory protection

Eye protection

Skin and body protecti jon

Use in well veñtilated area.

Approved respiratory equipment must be used when airborne

concentrations are unknown or exceed the recommended exposure limit. Self-Contained Breathing Apparatus may be required for use in confined or enclosed spaces.

If splash with liquid is possible, chemical type goggles should be warn,

If prolonged or repeated skin contact is likely wear oil impervious gloves

and clothing. 1f handling hot material use heat-resistant gloves, apron

and/or other clothing. Good personal hygiene practices should always be

followed.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Colour

Odour

Solubility

Boiling point

Flash Point

Vapour pressure

Relative vapour density

Density

Viscosity, kinematlc

Semi-solid,

Black

Characteristic

Immiscible

> 316 °C

> 230 °C (ASTM D-92)

< 0,1 hPa

16,0

> 1,01 g/em3 @ 20 °C (ASTM D-4052)

> 8.000 mm2/s @ 40 °C (ASTM D-445)Penetration Grade 35/50 Bitumen

10, STABILITY AND REACTIVITY

Stability

Conditions to avoid

Materials to avold

Hazardous decomposition

products

Stable.

Hot product in contact with water can cause foaming or sudden evolution of steam which could cause pressure buïld-up and possibly rupture a tank or vessel. Overheating may result in thermal cracking that produces toxic and flammable vapours,

Halogens, strong acids, alkalis and oxidizers.

Fumes, smoke, carbon monoxide, sulphur oxides, aldehydes.and other decomposition products, in the case of incomplete combustion.

11. TOXICOLOGICAL INFORMATION

Acute oral toxicity

Acute dermal toxicity

Acute inhalation toxicity

Skh irritation

Eye irritation

Respiratory and skin

sensitization

Gérm cell mutagenicity

Carcinogenicity

Reproductive toxicity

(Teratogenicity)

Specific target organ toxicity

(STOT) - singie exposure

Specific target organ toxicity

{STOT) - repeated exposure

Aspiration hazard

(Rats): Practically non-toxic.(LD50: Greater than 2000 mg/kg). Based on testing of similar products and/or components. Warning Hazard category 5. May be harmnful if swallowed,

(Rabbits): Practicaily non-toxic (LD50: “greater than 2000 mg/kg). Based on testing of similar products and/or the components. Warning Hazard category. 5. May be:harmful in contact with skin.

Not Established:

{Rabbits): Practically non-irritating. (Primary irritation Index: greater than 0.5 but less than 3). Based on testing of similar products and/or the components. Warning Hazard category 3. Causes mild skin irritation.

{Rabbits): Mid irritant. (Draize score: greater than 6 but 15 or less). Based on testing of similar products and/or the components. May cause mild eyeirritation. Hazard category 2B. Warning

This product was not a skin sensitizer when tested in a Modified Buëhler Guinea Pig Sensitization Assay.

This product tested negative in a serles of mutagenic tests.

Chronic mouse skin painting studies of straight run bltumen showed no evidence of carcinogenic effects. However, some bituminous compounds may contain low levels of polÿcyclic aromatic hydrocartions (PCAHS). Dilution with solvents and prolonged repéated contact under conditions of poor personal hygiene, are a suspected cause of skin cancer in humans.

Negative in a series of genetic assays and teratological studies.

No significant effects expected,

No significant adverse effects were found in studies using repeated dermal applications of bitumen to the skin of laboratory animals for 28 days at 2g/kg . Local dernal irritation and some welght loss was observed.

Inhalation studies of high concentrations of bitumen fumes in rodents produced bronchitis, pneumonitis and lung changes (fibrosis and celi damage).enetration 35/50

12. ECOLOGICAL INFORMATION

Écotoxicity effects

Toxicity to fish : Not.established.

Toxicity to aquatic : This substance 15 practically non-toxic to aquätic organisms (LL50: organisrms >1000 mg/l).

Elimination Information {persistence and degradability)

Biodegradability : Bitumené are persistent and not subject to biodegrädation.

Mobility : Adsorption to -sediment and soik will be the predominant behaviour.

Bioaccumulation : Minimal owing to low water solubility.

Further information on ecology

Remarks : In the absénce of specific environmental data for this product, this

assessment ls based on Information for representative substances.

43. DISPOSAL CONSIDERATIONS

Waste disposal : This product is suitable for recycling or safe disposal at approved

facilities.

Contaminated packaging : Ernpty containers retain residué (liquid and/or vapour) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,

GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS,

STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY

EXPLODE AND CAUSE INJURY OR DEATH, Do not attempt to refill or

clean container since residue Is difficult to remove, Empty drums should

be completely drained, properiy bunged and promptly returned to a

drum reconditioner. All containers should be disposed of in an

environmentally safe manner and In accordance with governmiental

regulations.

Other regulations : The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to

contain materials which are listed häzardous wastes. It does not exhibit

the hazardous characteristics of ignitability, corrosivity, or reactivity and

is not formulated with contaminants as determined by the Toxicity

Characteristic Léaching Procedure (TCLP). However, used product may

be regulated,

Flash Point î > 230 °C (ASTM D-92)

14. TRANSPORT INFORMATION

Note : Product may be transported by air of road If its temperature is below

200°C and îts flashpoint,

ADR

Proper shipping name 5 Eleväted Temperature Liquid, n.0.s, [contains ASPHALTS (PETROLEUM)] UN number î 3257

Class : 9

Packing group ï TI

Labelling number : 9

CFR

Proper shipping name : Élevated Temperature Liquid, n.0,s, [contains ASPHALTS (PETROËEUM)]

5Penetration Grade 35/50 Bitumen

UN number î 3257

Class ; 9

Packing group : AT

Labelling number: :

TATA_C

Proper shipping name ; Elevated Temperature Liquid, n.0.5. [contains ASPHALTS (PEFROLEUM)] UN number ! 3257

Class ï 9

Packing:group : nr

Labelling number :

IMDG

Proper shipping name : Elevated Temperature Liquid, n.0.s. [contains ASPHALTS (PEFROLEUM)] UN number : 3257

Class î 9

Packing group î AT

Eabelling number : 9

1MDG code page number : 9027-1

15. REGULATORY INFORMATION

US OSHA Hazard : This product may be used in certain applications where temperature may Communication Standard lead to generation of bitumen fumes.

Governmental Inventory : Al components comply with TSCA, EINECS/ELINCS, AICS, METI, DSL, Status KECI, ENCS, PICCS and IECSC.

EU Labelling : Product is not dangerous as defined by the European Union Dangerous Substances/Preparations Directives. EU labelling not required.

SARA

U.S. Superfund : This product contains no "EXTRÉMELY HAZARDOUS SUBSTANCES". Amendments and

Reauthorization Act SARA

Title TI

SARA (311/312) Reportable : None

Hazard Categories

The following product ingrédients are cited on the lists below

Chemical name THEN. Concentration [%] List Citations Asphalt 8052-42-4 100,00 1, 18, 19, 20, 21, 23, 25, 26

Regulatory List Searched

1 = ACGIH ALL 6 = IARC‘1 11 = TSCA 4 17 = CA P65 22.= MI 293 2 = ACGIH A1 7 = IARC2A 12 = TSCA 5a2 18 = CA RTK 3 = ACGIH A2 8 = IARC 2B 13 = TSCA 5e 19

4 = NTP CARC 9 = OSHA CARC 14 = TSCA 6 20 =ILRTK 25 = PARTK 5 = NTP SUS 10 = OSHA Z 35 = TSCA 12b 21 = LARTK 26 = RIRTK

Code Key: CARC = Carcinogen; SUS = Suspected Carcinogen

16. OTHER INFORMATION

Note: Engen products do not contain PCBs,Penetrati e 35/5 men

INJECTION INJURY WARNING: _If product Is injected into or under the skin, or into any part of the body, regardless. of the appearance of the wound or its size, the individual should be evaluated immediately by a doctor as à surgical emergency. Even though initial.symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.

Note: : No significant changes have been made to this Safetÿ Data Sheet since the previous däte.

Disclaimer

information given herein is offered in good faith as accurate, but without guarantee, Conditions of use and sultability. of the product for particular uses are beyond our control; all risks of use.of the product are therefore assumed by the user and we expressly dlsclaim ali warrantles of every kind and nature, including warranties of merchantability and fitness for a particular purpose in respect to the use or sultability of the product. Nothing. is intended as a récommiendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures shouid be provided to hendlers and users.

Prepared by :._ Product Safety Speclalist

Corporate Health, Safety, Environment and Quality Department

Engen Petroleum Limited

P,0.Box 35, Cape Town, 8000

Telephone : (021) 403 4805 / 4911 (Offlce Hours) (021) 403 4099 (After Hours)

083 628-4415 (Céllular)Penetration Grade 35/50 Bi n CP ENGEN

SAFETY DATA SHEET Revision Date : 01:04.2012

1: PRODUCT AND COMPANY IDENTIFICATION

Product name : Penetration Gràde 35/50 Bitumen Product use : Roadmaking and waterproofing

Supplier. : Engen Petroleum Limited (Tel: 021-403 4911, a/h: 021-403 4099) Health Emergency Telephone : --021-689 5227 (Red Cross Poison Service} Transport Emergency Telephone : 011-975 1278/83 (Hazchemwise) Customer Service Centre : “0860 036 436 (Sales and Technical Information) Engern Website : http://Www.engen.co.za/

2: HAZARDS IDENTIFICATION

Emergency response data : Black Semi-soïid. Exposure to fire can generate toxic fumes. DOT ERG No. 128

GHS Classification:

Health

Skin irritation Hazard category 3. Causes mild skin irritation. Warning Eye irritation Hazard category 2B. May cause miid eye irritation. Warning

Environmental

Aquatic toxicity : Insoluble product, no significant effects on the aquatlc environment,

Physical

Flammability : Non-flammable, combustible material.

GHS Labels/Pictograms:

Hazard Statements

Fumes from heated product may cause eye and lung irritation.. Hot product can cause thermal burns.

On rare occasions, Hydrogen Sulphide may be present which can accumulate to hazardous levels in enclosed

spaces,

Precautionary Statements

Response

IN CASE OF FIRE: use Carbon dloxide, foam or dry chemical for extinction, IF INHALED: Cail a POISON CENTRE or doctor if you feel unwell.

Disposal

Do not discharge into lakes, streams, ponds and ground water supply.

See Section 11 for further health effects/toxicological data.Penetratio. e 35/50 Bi

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name CAS-No. Weight%

Asphait 8052-42-4 100,00

See Section 8 for Exposure Limits (if applicable).

4. FIRST AID MEASURES

inhalation

Skin contact

Eye contact

Ingestion

Under certain conditions smoke may be generated. Remove victim From further exposure. However; if respiratory irritation occurs due to excessive vapour or mist exposure, seek immediate medical assistance. 1f breathing has stopped, assist ventilation with mechanical device or use moüth-to-mouth resüscitation,

Hot product can cause thermal burns. Immediately coo! the affected area with water. This will form a sterlle cover over the burn. Rémoval of cooled product should not be attempted unless directed by a burns specialist,

1f hot product is splashed into eyes flush with water and get immediate medical attention.

Not expected to be a problem. However, if discomfort occurs seek medical attention.

5. FIRE-FIGHTING MEASURES

Extinguishing media

Special fire fighting

pracedure

Special protective

équiprent for flrefighters

Unusuai fire and explosive

hazards

Products of decomposition

Flash Point

NFPA Hazard Id

Carbon dioxide, foam and dry chemical.

Water may cause a rapid expansion of foaming material. Water spray should only be used to keep fire exposed containérs coo! and to flush spllls away from exposure. Prevent runoff from fire control or dilution from entering streams, municipal sewers, or drinking water supply.

Minimise inbaling fumes.of décomposition products, and in enclosed

areas, firé fighters must use Self-Contained Breathing Apparatus,

Exposure to fire can generate toxic fumes.

Fumes, smoke, carbon monoxide, sulphur oxides, aldehydes and other decomposition products, in the case of incomplete combustion.

> 230 °C (ASTM D-92)

Health: 3; Flammability: 0; Reactivity: 0

6. ACCIDENTAL RELEASE MEASURES

Procedure if material is

released or spilled

Methods for cleaning up

Personal precautions

Report spitls/reléases as required to appropriate authorities.

LAND SPILL: Shovel up and dispose of at an appropriate waste disposal facility in accordance with current applicable laws and regulations, and product characteristics at time of disposal.

WATER SPILL: Bitumens are Immiscible with water but may be adsorped In the sediment. Surface material may be skimmed off for later disposal.

See Section 8,Penetration Grade 35/50 Bitumen

Environmental precautions Prevent spill from entering municipal sewers and water sources as Ît may cause blockages. Advise the relevant authoritles if contaminations

have occurred.

7. HANDLING AND STORAGE

Safe handling advice ï

Storage information

Storage and handling

procedures

On'rare occasions, Hydrogen Sulphide may be present which can accumulate to hazardous levels in enclosed spaces. Avoid ali personal contact and breathing of gas,

Adequately vented storäge tanks should be mäintalned below 100°C ta prevent evolution of Hydrogen sulphide or degradation of the product.

Avoid local overheating when raising to pumping temperature.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Occupational Exposure Limits (OELS)

Components CAS-No. Source TWA Value Notations

Asphalt 8052-42-4 ACGIH TLV | LTEL 0,5 mg/m3 Fumes

LTEL: Long Term Exposure Limits - Time Welght Average (TWA) over 8 hours.

STEL: Short Term Exposure Limits - Time Weight Average (TWA) over 15 Minutes

Note: Limits Shown for guidance only, Follow applicable regulations,

Personal Protection Equipment (PPE}

Engineering controls

Respiratory protection

Eye protection

Skin and body protection

Use iri well ventilated area.

Approved respiratory equiprent must be used when airborne

concentrations are unknown or exceed the recommended exposure limit, Self-Contained Breathing Apparatus may be required for use in confined or enclosed spaces,

If splash with liquid is possible, chemical type goggles should be worn.

F prolonged or repeated skin contact is likely wear oïùl impervious gloves and clothing. f handling hot material use heat-resistant gloves, apron and/or other clothing. Good personal hygiene practices should always be followed,

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearancé

Colour

Odour

Solubitity

Boiling point

Flash Point

Vapour pressure

Relative vapour density

Density

Viscoslty, kinematic

Semi-solid,

Black

Characteristic

Immiscible

> 316 °C

> 230 °C (ASTM D-92)

<-0,1 hPa

16,0

> 1,01 g/cm3 @ 20 °C (ASTM D-4052)

> 8.000 mm2/s @ 40 °C (ASTM D-445)Penetration Grade 50 Bitume:

10, SFABILITY AND REACTIVITY

Stability

Conditions to avoid

Materials to avoid

Hazardous decomposition

products

Stable.

Hot product in contact with water can cause foaming or sudden evolution

of steam which could cause pressure build-up and possibly rupture a

tank or vessel, Overheating may result in thermal cracking that

produces toxic and flammable vapours.

Halogens, strong acids, alkalis and oxidizers.

Fumes, smoke, carbon monoxide, sulphur oxides, aldehydes and other decomposition products, in the case of incomplete combustion:

11. TOXICOLOGICAL INFORMATION

Acute orai toxicity

Acute dermal toxicity

Acute inhalation toxicity

Skin (rritation

Éye irritation

Respiratory and skin

sensitizatlon

Germ céll mutagenicity

Carcinogenicity

Reproductive toxicity

(Teratogenicity}

Specific target organ toxicity

(STOT) - single exposure

Specific target organ toxicity

(STOT) - repeated exposure

Aspiration hazard

(Rats): Practically non-toxic (LD50: Greater than 2000 mg/kg). Based

on testing of similar products and/or components, Warning Hazard

category 5. May be harmful if swallowed.

(Rabbits): Practically non-toxic (LDS0: greater than 2000 mg/kg). Based on testing of similar products and/or the components. Warning Hazard category. 5. May be‘ harmful in contact with skin.

Not Established.

(Rabbits): Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). Based on testing of similar products and/or the components, Warning Hazard category 3. Câuses mild skin irritation.

{Rabbits): Mild irritant. (Draize score: greater than 6 but 15 or less). Based on testing of similar products and/or the components. May cause mild eye irritation, Hazard category 2B. Warning

This product was not a skin sensitizer when tested in a Modified Buehler

Guinea Pig Sensitization Assay.

This product tested negative in a series of mutagenic tests.

Chronic mouse skin painting studies of straight run bitumen showed no evidence of carcinogenic effects. However, some bituminous compounds may contain low levels of polycyclic aromatic hydrocartions (PCAHS). Dilution with solvents and prolonged repeated contact under conditions of poor personal hygiene, are a suspected cause of skin cancer in humans.

Negative in a series of genetic assays and teratological studies.

No significant effects expected.

No significant adverse effects were found in studies using repeated dermal applications of bitumen to the skin of laboratory animals for 28 days at 2g/kg. Local dermal irritation and some welgfit loss was observed.

Inhalation studies of high concentrations of bitumen fumes in rodents

produced bronchitis, pneumonitis and lung changes (fibrosis and cell damage).Penétration Grade 35/50 Bitumen

12. ÉCOLOGICAL INFORMATION

Ecotoxicity effects

Toxicity to fish

Toxlelty to aquatic

crganlsms

Not established,

This substance is practically non-toxic to aquatlc organisms (LLS0: >1000 mg/l).

Elimination information (persistence and degradability)

Biodegradability

Mobility

Bloaccumulation

Further information on ecology

Remarks

Bitumens are persistent and not.subject to biodegrädation.

Adsorption to sediment and soit will be the predominant behaviour,

Minimal owing to low water solubility.

In the absence of specific environmental data for this product, this assessment is based on Information for representative substances.

13. DISPOSAL CONSIDERATIONS

Waste disposal

Contäminated packaging

Other regulations

Flash Point

This product Is suitable for recycling or safe disposal at approved

facilities.

Empty containers retain residue (liquid and/or vapour) and can bè

dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH, Do not attempt to refill or clean container since residue is difficult to remove, Empty drums should be completely drained, properly bünged.and promptly returned to a drum reconditioner. All containers should be disposed of in an

environmentally safe manner and in accordance with governmiental regulations.

The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formuläted to contain materials which are listed hazardous wastes, It does not exhibit the hazardous characteristics of ignitability, corrosivity, or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure {TCLP). However, used product may be regulated.

> 230 °C (ASTM D-92)

14. TRANSPORT INFORMATION

Note

ADR

Proper Shipping name

UN number

Class

Packing group

Labelling number

CFR

Proper shipping name

Product may be tränsported by air or road if its temperature is below 100°C and its flashpoint,

Elevated Temperature Liquid, n.0.s. [contains ASPHALTS (PÉTROLEUM)] 3257

9

UT

9

Elevated Temperature Liquid, n.0.s. [contains ASPHALTS (PETROLEUM)]

sPenetration Gra 50 Bitumen

UN number : 3257

Class ; 9

Packing group : IL

Labelling number :

IATA_C

Proper shipping name ; Elevated Temperature Liquid, n.0.s. [contains ASPHALTS (PETROLEUM)] UN number. î 3257

Class î 9

Packing group : IE

Labelling number ;

IMDG

Proper shipping name 3 Elevated Temperature Liquid, n.0.5. [contains ASPHALTS (PETROLEUM)] UN number ; 3257

Class : 9

Packing group : HT

Labelling number ‘ 9

IMDG code page number : 9027-1

15. REGULATORY INFORMATION

US OSHA Hazard : This product may be used in certain applications where temperature may Communication Standard lead to generation of bitumen fumes.

Governmental inventory : AU components comply with TSCA, EINECS/ELINCS, AICS, METE, DSL, Status KECI, ENCS, PICCS and IECSC.

EU Labelling : Product is not dangerous as defined by the European Union Dangerous

Substances/Preparations Directives. EU labelling not required,

SARA

U,S, Superfund : This product contains no "EXTREMELY HAZARDOUS SUBSTANCES". Amendments and

Reauthorization Act SARA

Title III

SARA (311/312) Reportablé - : None

Hazard Categories

The following product ingredients are cited on the lists below

Chemical name CAS-No. Concentration [%1 List Citations

Asphalt 8052-42-4 100,00 4,18, 19, 20, 21, 23, 25, 26

Regulatory List Searched

1 = ACGIH AiL 6=IARCI 11 = TSCA 4 17 = CA P65 22 = MI 293

2 7 = IARC 2A 12 = TSCA 5a2 18=CARTK 23 = MN RTK

3 = ACGIH A2 8 = IARC 2B 13 = TSCA 5e 19 = FLRTK 24 = NJ RTK

4 = NTP CARC 9 = OSHA CARC 14 = TSCA 6 20 =ILRTK 25 = PA RTK

5 = NTP SUS 10 = OSHAZ 15 = TSCA 12b 21 = LA RTK 26 = RIRTK

Code Key: CARC = Carcinogen; SUS = Suspected Carcinogen

16. OTHER INFORMATION

Note: Engen products do not contain PCBs.trati 50.Bi

INJECTION INJURY WARNING: ff product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the Individual should be evaluated immediately by a doctor as a surgical emergency. Even though Initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.

Note: No significant changes have been made to this Safety Data Sheet since the previous date.

Disclaimer

Information given herein..is offered In good falth as accurate, but without guarantee, Conditions of use and suitabllity .of the product for. particular uses are beyond our control; ail risks of use of the product are therefore assumed by the user and we expressly disclaim all warrantles of every kind and nature, including warranties of merchantability and fitness for a particular purpose in respect to the use or suitabliity of the product. Nothing Is intended as a recommendation. for -usés-which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to hañdlers and users.

Prepared by : Product Safety Specialist

Corporate Heaïth, Safety, Environment and Quality Department

Engeni Petroleum Limited

P.0.Box 35, Cape Town, 8000

Telephone : (021) 403 4805 / 4911 (Office Hours)

{021} 403 4099 (After Hours)

083 628 4415 (Cellular)PENET N GRA 0/50 B

© ENGEN

MATERIAL SAFETY DATA SHEET Revision Date: 01.06.2008

1. PRODUCT AND COMPANY IDENTIFICATION

Product name

Product use

Suppiler.

Health Emergency Telephone

Transport Emergency Telephone

Customer Service Center

MSDS Internet website

PENETRATION GRADE 40/50 BITUMEN

Rosdmaking and waterproofing

Engen Pétroleum Limited (Tel: 021-403 4911, a/h: 021-403 4059)

021-658 5111 (Red Cross Poison Service)

011-975 1278/83 (Hazchemwise)

0860 036 436 (Sales and Technical Information)

wiww.engen.co.za/content/products/default2.htm

2. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name CAS-No. Weight%o Symbol R-Phrase Numbers

Codes

Asphait 8052-42-4 100.00

See Section 15 for European Label Information,

See Section 8 for Exposure Limits (If applicable).

3. HAZARDS IDENTIFICATION

Emergency response data

Potentlal health effacts

Inhafation

Skin

Eye

Black Semi-solid. Exposure to fire can generate toxic fumes. DOT ERG

No.: 128

Irritetion may be caused if exposed to high concentration of fumes

evolved when material is heäted. Hydrogen suiphide may be present

which can accumulate to hazardous levels in enclased spaces.

Hot product can cause thermal burns.

Irritatlon may be caused IF exposed to-high concentration of fumes

evoived when matérlal Is heated.

See Section 11 for further health effects/toxicological data.

4, FIRST AID MEASURES

Inhalation

Skin contact

Eye contact

Ingestion

Under certain conditions smoke may be generated. Remove victim from

further exposure, However, If respiratory irritation occurs due ta

excessive Vapour or mist exposure, séek immédiate medical assistance.

If breathing has stopped, assist ventilation with mechanical device or use

moëth-to-mouth resuscitation.

Hot product can cause thermal burns. immediately cool the affected

area with water, Removai of cooled product should not be attempted

unless directed by a burns specialist.

If hot product is splashed into eyes flush with water and get immediate

medical attention.

Not expected to be a problem. However, If discomfort occurs seek

medical attention.

5. FIRE-FIGHTING MEASURESPENETRATIO

Éxtinguishing media

Special fire fighting

procedure

Special protective

equipment for firefighters

Unusual fire and explosive.

hazards

Products of decomposition

Flash Point

NFPA Hazard Id

Carbon dioxide, foam and dry chemical,

Water may cause à rapid expansion of foaming material. Water spray should only. be.used to keep fire.exposed containers cool and to flush spills away from exposure. Prevent runoff from fire control or dilution from:entering streams, municipal sewers, or drinking water supply.

Minimise inhaling fumes of decomposition products, and in enclosed

areas, fire flghters must use Self-Cantained Breathing Apparatus.

Exposure to fire can generate toxic fumes.

Fumes, smoké, carbon monoxide, sulphur oxides, aldehydes and other decomposition products, in the case of incomplete combustion.

> 230 °C (ASTM D-92)

Health: 3; Ffammability: 0; Reactivity: 0

6. ACCIDENTAL RELEASE MEASURES

Procedure if material is

released or spilled

Methods for cleaning up:

Personal precautions

Environmental precautions

Report spills/releases as required to appropriate authorities.

LAND SPILL: Shovel- up and dispose of at an appropriate waste disposal facllity in accordance with current applicable laws and regulations, and product characteristics at time of disposal.

WATER SPILL: Bitumens are immiscible with water but may be adsorped In the sediment.. Surface material may be skimmed off for later disposal.

See Section 8.

Prevent spiil from entering municipal sewers and water sources as it may cause blockages, Advise the relevant authorities if contaminations have occurred.

7. HANDLING AND SFORAGE

Safe handling advice

Storage information

Storage and handling

procedures

Hydrogen sulphide may be present which can accumulate to hazardous levels in enclosed spaces. Avoid all personal contact and breathing of ges.

Adequately vented storage tanks should be maintained below 100°C to prevent evolution of Hydrogen sulphide or degradation of the product.

Avoid local overheating when faising to pumping temperature,

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Occupational Exposure Limits (OELs}

Components CAS-No, Source TWA Value Notations

Asphalt 8052-42-4 ACGIH LTEL 0.5 mg/m3 Fumes

LTEL: Long Term Exposure Limits - Time Weight Average (TWA) over 8 hours,

STEL: Short Term Exposure Limits - Time Weight Average (TWA) over 15 Minutes

Note: Limits Shown for guidance only. Follow applicable regulations.

Personal Protection Equipment (PPE)

Engineering controls Use in well ventilated area.RATI RAD

Respiratory protection

Eye protection

Skin and bôdy protection

50 BITU

Approved respiratory equipment must be used when alrborne .

concentrations are unknown or exceed the recommended exposure |imit.

Self-Contained Breathing Apparatus may be required for use in confined

or enclosed spaces.

If splash with liquid is possible, chemical type gogglés should be worn.

1f prolonged or repeated skin contact is likely wear oil Impervious gloves

and clothing. If handling hot material use heat-résistant gloves, apron

and/or other clothing. Good personal hygiene practices should always be

ollowed.

9. PHYSICAL AND CHÉMICAL PROPERTIES

Appeararice

Colaur

Odour

Solubility

Boïling point/range

Fiash Point

Vapour pressure

Relative vapour density

Density

Viscosity, kinematic

Semi-solid,

Black

Characteristic

Immiscible

> 316 °C

> 230 °C (ASTM D-92)

< 0.1 hPa

16.0

>1.01g/em3 @ 20 °C (ASTM D-4052)

>-8,000 mm2/s @ 49 °C (ASTM D-445)

10. STABILITY AND REACTIVITY

Stability

Conditions to avoid

Materials to avoid

Hazardous decomposition

products

Stable.

Hot product in contact with water can cause foaming or sudden evolution

of steam which couid cause pressure build-up and possibly rupture a

tank or vessel. Overheating may result in thermal cracking that

produces toxic and flammable vapours.

Halogens, strong acids, alkalis and oxidizers,

Fumes, smoke, carbon monoxide, sulphur oxides, aldehydes and other

decomposition products, in the case of Incomplete combustion.

11. TOXICOLOGICAL INFORMATION

Acute oral toxlcity

Acute Inhalation toxlcity

Acute dermal toxicity

Skin irritation

Eve irritation

Other acute toxicity data

Sensitization

Repéated dose toxlclty

(Rats): Practicaily non-toxic (LD50: Greater than 2000 mg/kg). Based

on testing of similar products and/or components.

Not Established.

(Rabbits): Practically non-toxic (LD50: greater than 2000 mg/kg).

Based on testing of similar products and/or the éompanents.

{Rabbits): Practicaily non-irritating. (Primary Irritation Index: greater

than 0.5 but less than 3). Based on testing of similar products and/or

the components.

{Rabbits): Practically non-irritating. (Draize score: greater than 6 but

15 or less). Based on testing of similar products and/or the components.

Hydrogen sulphide acts as à chemical asphyxlant, preventing the body

from utilizing oxygen in the tissue. It can be irritating to the eyes at 10

ppm and to the respiratory tract at 50-100 ppm after 1-hour exposure,

Loss of sense of smell at 100 ppm, drowsiness, loss of consclousness,

respiratory failure ar death can result from exposure above 100 ppm.

This product was not a skin sensitizer when tested In a Modified Buehler

Guinea Pig Sensitization Assay.

No significant adverse effects were found in studies using repeated

dermal applications of bitumen to the skin of laboratory animals for 28

3PENETRATION GRADE 49/50 BITUMEN_

days at 2g/kg. Local dermal Irritatlon and some weight loss was observed.

Carcinogenicity ! Chranic mouse skin painting studies of straight run bitumen showed no evidence of carcinogenic éffects, However, some bituminous compounds may contain low. levels of polyaromatic compounds (PACS). Dilution. with solvents and prolonged repeated contact under conditions of poor personal hygiene, are a suspected cause of skin cancer in humans.

Other toxicological : Inhalation studiés of high concentrations. of bltumen fumes in rodents information produced bronchitis, preumonitis and lung changes (fibrosis and cell damage).

12. ECOLOGICAL INFORMATION

Elimination information (persistence and degradabitity)

Biodegrädability : Bitumens are persistent and not subject to biodegradation.

Physico-chemical : Adsorption to sedimerit and soil wiil be the predominant behaviour. removabllity

Bioaccumulation ! Minimal owing to low water solubility.

Ecotoxicity effects

Toxicity to aquatic ï This substance Is practically non-toxic to aquatic organisms (LLS50 >1000 organisms mg/f}.

Further information on ecology

Remarks : In the absence of specific environmental data for this product, this assessment is based on information for representative substances.

13. DISPOSAL CONSIDERATIONS

Waste disposal : This product is suitable for recycling or safe disposal at approved facilities.

Contaminated packaging : Empty containers retain residue (liquid and/or vapour) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY. EXPLODE AND. CAUSE INJURY OR DEATH. Do not attempt to refill or clean container since residue Is difficult to remove. Empty drums should be comptetely dralned, properly bunged and promptly returned to a drum reconditioner. All containers should be disposed of In an environmentally safe manner and in accordance with governmental regulations.

Other regulations ! The unused product, in our opinion, Îs not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is It formulated to contain materials which are listed hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrosivity, or reactivity and Îs not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP}). However, used product may be regulated.

Flash Point ! > 230 °C (ASTM D-92}

14. TRANSPORT INFORMATION

Note : Product may be transported by air or road if its temperature is below 100°€ and its flashpoint,

ADR

Proper shipping name : Elevated Temperature Liquid, n.0.s. [contains ASPHALTS (PETROLEUM)] UN number : 3257

4PENETRATION GRADE 40/50 BITUMEN

Class

Packing group :

Labelling number !

CFR

Proper shipping name

UN number

Class

Päcking group

Labelling number

IATA_C

Proper shipping name

UN number

Class

Packing group

Labelling number

IMDG

Proper shipping name

UN number

Class

Packing group

Labelling number

IMDG code page number

s

UT

9

Elévated Temperature Liquid, n.0.s. [contains ASPHALTS (PETROLEUM)] 3257

9

UT

Elevated Temperature Liquid, n.0.s. [contains ASPHALTS (PETROLEUM)] 3257

s

I

Elevated Temperature Liquid, n.0.s. [contains ASPHALTS (PETROLEUM)]

3257.

g

IL

9

9027-1

15. REGULATORY INFORMATION

US OSHA Hazard

Communication Standard

Governmental Inventory

Status

EU Labelling

SARA

U.S, Superfund

Amendments and

Reauthorization Act SARA

Title III

SARA (311/312) Reportable

Hazard Categories

This product may be used in certain applications where temperature may

lead to generation of bitumen fumes.

All components comply with TSCA, EÎNECS/ELINCS, AICS, METI, DSi,

KECI, ENCS, PICCS and IECSC.

Product is not dangerous as defined by the European Union Dangerous

Substances/Preparations Directives, EU labelling not required.

This product contains no "EXTREMELY HAZARDOUS SUBSTANCES",

None

The following product ingrédients are cited on the lists below

Chemical name CAS-No. Concentration [%] List Citatlons

Asphalt 8052-42-4 100.00 1, 18, 19, 20, 21, 23, 25, 26

Regulatory List Searched

1 = ACGIH ALL 6 =]IARC 1 11 = TSCA 4 17 = CA P65 22 = MI 293

2 = ACGIH A1 7 = IARC 2A 12 = TSCA 5a2 18 = CA RTK 23 = MN RTK

3 = ACGIH A2 8 = ARC 2B 13 = TSCA 5e 19 = FLRTK 24 = NI RTK

4 = NTP CARC 9 = OSHA CARC 14 = TSCA 6 20 = IL RTK 25 = PARTK

5 = NTP SUS 10 = OSHAZ 15 = TSCA 12b 21=LARTK 26 = RIRTK

Code Key: CARC = Carcinogen; SUS = Suspected Carcinogen

16. OTHER INFORMATION

Note: Engen products do not contain PCBs.

Health studies have shown that many hydrocarbons pose potential human health risks which may vary from

5PENET D B MEN

person to person. Information provided on this MSDS reflects intended use. This.product should not be used or any other applications. In any case, the following advice should be considered:

INJECTION INJURY WARNING: _ If product Is Injected into or under the skin, or into any part of the body, regärdless of the appearance of the wound.or its size, the Individual should be evaluated immediately by a doctor as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgicat treatment within the first few hours may significantly reduce the ultimate extent of injury.

Precautionary Label Text:

Contains Bitumen.

CAUTIONI

SAFETY: Exposure to high fume concentrations from heated product may cause eye and respiratory tract infection. Toxic hydrogen sulphide may be released. Hot product may cause thermal burns and form flarmmable vapours when contained.

FIRST AID: Under certain conditions smoke.maÿ be generated. Remove victim from further exposure. However, if respiratory irritation occurs due to excessive vapour or mist exposure, seek immediate medical assistance. If breathing has stopped, assist ventilation with mechanical device or use mauth-to-mouth resustitation. Hot product can cause thermal burns. Immediately cool the affected area with water, Removal of cocted bitumen shouid not be attempted.unless directed by a burns speclalist. If hot product is splashed into eyes flush With water. and get immédiaté medical attention,

For industrial use only. -Not intended or suitable for use in or around a household or dwelling.

Disclaimer

Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control; all risks of use of the product are therefore assumed by the user and we expressly disctaim ail warranties of every kind and nature, including warranties of merchantability and fitness for a particular purpose in respect to the use or suitability of the product. Nothing is intended as à recommendation for uses which infringe valid patents or as extending license under valid patents, Appropriate warnings and safe handling procedures should be provided to handlers and users,

Prepared by : Product Safety Adviser

Health, Safety, Environment and Quality Department

Engen Petroleum Limited

P.0.Box 35, Cape Town, 8000

Telephone : (021) 403 4805 / 4911 (Office Hours) (021) 403 4099 (After Hours)

083 628 4415 (Cellular)BRENNTAG EXPORT

PROFORMA INVOICE

INGÈNIERIE BETON SYSTEME SA (185) Page:

CARRIERE DE KANGANI BP 429

97600 MAMOUBZOU

Mäyotte

Vitrolles lé 1 03-02-2010

PROFORMA INVOICE NO. : 10030896 21, bd de l'Europe, B.P 60026

Votre référence : mail 26/01 69 COM Vitrolies: France

CONTRAT NO. : 10030396

MATERIAL / PACKING / QUANTITY TOTAL EUR

Spécification 3 AGIDE CHLORHYDRIQUE 32-34%

ORIGINE : FRANCE

HS code : : 28061000

DRUG PRECURSORS (REGULATION 1134/2008 EC}

Emballagé ‘8 fûts métal de 234 kgs net, 8.424 kgs tare Quantité : -1:872,000 kgs net

Pix : EUR 765,00 la tonne métrique net 1.413,36

1.419,36

EXONERATION DE T.V.A :CGI : ART, 261 1

L'exportateur des produits éauverts par le présent document déciare que,sauf indication claire du contraire,ces produits ont l'origine préférentielle Union-européenns.

Destination Finale : MAYOTTE

Lieu de livraison : AMIENS

Marques : ACIDE CHLORHYDRIQUE 32-34%

NET : 234 KGS/

Conditions de livraison : .FCA AMIENS

Conditions : In EUR nett par avance.

de paiement

Bank : Sacieté Generale, Marseille Acc. No. 0002515734 { EUR) Swift/BIC : SOGEFREPP IBAN : FR76 30008 01276 00025155734 74

Bronotsg Export SARL. 21, bd de l'Europe Tél. +93 (4} 42 48 22 42 SARL au cépitel de 783 000 Euros

.P, 80026 Fax + 83 (4) 42 48 22 09 N° TVA: FR 86 452 285 664 18744 Virolss export @branntagerpar com RCS Selon 452 265 664 00016 Francs A DreNnlAgéx por Com General condilions an the back Corditions Générales au versa

Member of Brennlag Export Wii iocalons In Belgium, France

nd te Nelherand.D Shell Chemicals

Material Safety Data Sheet

ShellSoi 2325

Vetston 3,1

Effective Date 16.02.2007

according (o EG directive 2001/5840

1, IDENTIFICATION OF. THE SUBSTANCE/PREPARATION AND COMPANV/UNDERTARINS

Materia| Name

Uses

Praduct Code

Manufacturer{Supplier

Telephone

Fax

Emergency Telephone :

Number

Other Information

: Shel!Soi 2325

Industrial Solvent.

03851

Shell South Africa Chemicals

Reunian Rocks Raäd

4310 Isipingo

South Africa

+27 (0)31 013 2000

+270)31 902 5228 / 902 5768

South Afica :+27 (0)31 002 4075 or +27 {0} 836291307

Zimbabwe : Normal: (04) 703115/147 or 011 200072/73 Kenya

:0825411 491 328

ShellSol is a trademark owned by Shell Frademark

Mañegement Ê,V. and Shell Brands ic, and used by affllates

of Royal Dutch Shelt ple.

2. COMPOSITIONINFORMATION ON INGREDIENTS

Material Formal Name

CAS No.

INDEX No.

EINEGS No.

Kerosine (pstralèum), hydrodesulfurizéd

64742-81-Q

649-423-00-8

265-1845

3. HAZARDS IDENTIFICATION

Héaith Hazards

Signs and Symptomis

Environmental Hazarcts

7 covrd

May cause macerate imitation to skin, Repeated exposure may

cause skin dryness or cracking, Harmfut: may cause lung

damage if awvallowad, Posstbility of ofgan or organ system

damage from prolonged exposure: see ‘Chapter 11 for details.

a. ergan(s): Auditory system, Central nervous system

CNS}.

Defatting dermatitis sfgns anc symptomes may include a

burniig sensation and/or a dried/cracketi éppesrance. Other

sions and sympioms of central nervous system (GNS)

del nelude.heatache.-nauées-and{eck-df

igns and symptoms may tion, Respiratory tritation

coughing, and/or difficult breathing

Expected o be harmful t aquatic Grganisme, May cause long-

term ädverss effécts In fé aquallc environment,

Print Date 20.06.2007 UT

MSDS, ZA(RU) Shell Chemicals

Materlal Safety Data Sheet

Effeotive Uté 16.02.2007

ecco#ding to EC directive 2001/E8/EC

4. FIRST AID MEASURES

inhalation

Skin Contact

Eye Contact

î Ingestion

Advice to Fhysician

Remove to fresh air. frapid racovery does not onçur, transport

to nearest medical facility for additional treatment.

Reriove coniaminated clothing, Fluskexposed arsa with water

and follow by wastilng with soap if available,

Flush eye with coplotis quantities of water, If persistant

Imitation occurs, obtaln médiaal attention.

iFswaällowed, do nat induce vorniting: transport to nearest

medical facility far additional trestment. fYomiting occurs

spantanéously, kéep head below hips to prévent aspiration.

Causes central nervous system dépression. Dermatilis may

resulé from prolongad or repeatad exposure, Potentlal for

chemical.pneuronitis. Gansider gastric lavage with protected

alrWey, administration of aclivated.charcoal. Call a doctor ar

polsôñ control céñter for guidance.

5. FRÈ FIGHTING MEASURES

Clear fire area of all non-emergency pérsonnel,

Specific Hazards

Extiagutshing Media

Unsulteble Extinguishing

Media

Profactive Equipment for

Firsfighters

Additional Advice

Carbon monoxide may be-evolved if Incomplete combustion

océurs. Will float arid can he réignitéd on surface water. The

vapour Îs heavier than air, spreads along the ground and

distant ignitlon is possible.

Foañ, wäter spray or fog. Dry chémical powder, carbon

dioxide, sand or earlh may be used for small fires onlÿ. Do nat

discharge extingulshing waters into the aquatic environment.

Da not.use water in a jet.

Wear full protective clothing.énd self-contained breathing

apparalus.

Keëp adjacent containérs cool by spraying with water.

6. ACCIDENTAL RÉLEASE MÉASURES

©

Protectivé measures

Gbserve all rélevant local and intarmäationai regulations.

Avoid céntact with spllled ar released material, immediately

remove all contaminated élathing. For guidance on selection of

personal protéctivé equipment sëe Chapter 8 of this Material

Safety Däte Sheet. For guidance oh disposal of spilled material

see Chapter 18 of this Material Safaty Data:Sheot. Shut off

. feaks, if possible without personsi risks Renidve all-pèssibte

sources of lgnition in {he surrounding ares, Use appropriate

santaiamoent(ofpraductand-fi

environmental contarinatl

de

ravent for spreading or

appropriate barrièrs. Attermnpt to disperse the vapaur or to direct

HS. flow to a safe location for example by using fog spraÿs.

Take précautlonery méasures agälnst static discharge. Ensure

electrieal continulty by sonding añd grounding {earthing) ait

Point Date 20.06.2007

27 MSDS_ZA@ Shell Chermicals

} Material Safety Data Sheet

Clean Up Methods

Additional Advice

SheliSol 2325

Version 3.4

Efective Date 16.02.2007

accordig lo-EC directivé 200 1/5B/EC

equipment.

Fer smiall quid splits < 1 drum), transfer by mechanical means

to a fabslled, sealable container for product recovery or safe

disposal. Allo restdues to evaparate or soak up with an

appropriate absorhent materlal and dispose of safely, Remove

conteminaled soll and dispase of safély.

For large liquid splits (> À drum), transfer by mechanital meatis

Such-a5 vacuum.buck to a salvage tank for recovery or safe

disposal. Do not flust away residues with water. Retaïn as

contaminated waste, Allow'residués to-evaporate ar soak up

with an appropriate absarbent matetial and dispose of safely.

Remove contaminated sol arid.dispose of safaly.

See Chaptar13 for information on disposal. Notify authorities If

any sxpoëre to fie general public or lhe environment cecurs

oris.ilkely to ocour,

T7. HANDLING AND STORAGE

General Précautions

Handiing

Storage

Product Transfer

Récommended Materials

Unsuitablé Materials

Confatner Advice :

Additional Inforraation

Avald breathlng vapours or contaot with material, Only use ln

well ventilated éreas. Wash thoroughly after haridling. On

guidance on sélection of personal prolective equipment see

Ghäpter 8 ofthis Mateñal Séfety Data Shéet. Use the

Inforraation in this date sheet.as input lo a risk assessment of

lobal circumstances to help determine appropriate controls for

safe handling, storage and disposal of this material.

Av6id.coritaût with: in, eyes, and élothing. Handle ant open

container with care in a well-ventitäted area, Ventilate

woikplace in such a way that the Occupational Exposure Limit

(OËL) is nol excssded. Do not empty into drains.

Must bé stored in à diked (hunded) area. Bulk Storage tanks

should be diked {unded). Storage Temperature: Ambient,

Meximum storage me: 6 months

H positive displacoment pumps:are used, these must be fited

with a nôn-intégral pressure relléf valve. Electrustatic Gfiarges

may. be generated during pumping. Electrostatié discharge may

causa fre.

For containers, or container linings use mitld steel, stainless

steel, For container paints, use:epoxy paint, zinc sllicate paint,

Avoild prolonged contact with natural, butyl or nitrile rubbers,

Coriälners, aven thosé that have been emptied, can oontain

explosive vapours. Da not cut, drifl, grind, weld or perform

siitar dperatlons on or near containers.

Ensure that all local regulatlons regarding hendling and storage

faciles are followed.

6. EXPOSURE CONTROLS/FERSONAL PROTECTION

SenCe 0!

following are adopited.

UK Workplace Exposure Limits

dccupalonal exposure standar

Occupational Exposure Limits

Print Date 20.06.2007

at

MSDS, ZAShellSol 2225 @ Shell Chemicüls Version 3.1

Effects Date 16.02.2007

Material Saféty Data Sheet according to EG dheclive 2001/58/EC

11. TOXICOLOGICAL INFORMATION

Basls for Assessment : information given is based on product testing, and/or sirrllar

products, and/or components,

Acute Oral Toxicity 2 Expected to be of low toxicity: LDSD >2000 mglkgq , Rat

Aspiration into the lungs when swallowed or vomited may

cause chemical preumonitis which can be fatal.

Acute Dermal Toxitity : Expected to ba of low toxicity: LD50 22000 mg/kg , Rat Acute Inhalation Toxicity . : Expected to be of low toxicity: LCS0 gréater than near: saturäled vapour concentration, / 4 hours, Rat

‘Skin Irritation +: May cause moderate skin kritation (but insufficient to classify).

Pralonged/repeated contact may. cause defatting of the skin

‘ which can lead to derrnalitis.

Eye trritation 2: Expécted to be non-imitating to eyes.

Respirätory Irétation #Inhalation of vapors or mists may cause trritat{on to.the

respirätory system.

Sensitisation : Not expected to be a skin sensitisr,

Repenteë Dose Toxicity: : Kidney: caused kidney effects In male rate which are riot

considered relevant to humans Auditary system: prolonged anû

repeated exposuras fo hlgh-cancentrations have resulted in

héaïtrg loss în rats, Solvent abyse and noise interaction In the

work environment may cause hearing loss, Central nervous

system: repealed exposure stfects the nervous system.

Mutagenicity :_ Not expected to be mutagents.

Reproductivé and 2 Causes fostotoxicity In animials at doses which are matemally Déeveloprmientat Toxicity toxic.

Not expected to impair fertility.

12. ECOLOGICAL INFORMATION

Acute Toxicity

Fish Expected to be harmful: 10 < LC/EC/IC60 <& 100 mgil Aquatic invertebrates Expected to have low toxlclty: LO/ECACS0 > 100 mg/l Algae Expected to be harmfui: 10 < LG/EC/ICSD <= 100 mgfl Microcrganisms Expected to be hannful: 10 < LC/EC/ICE0 <= 100 mg/l G Mobiltiéy : Floats on water,

. Adsorbs to soif and has low mobility. Persistencé/degradability : Oxidises rapidly by phota-chemical réactions in air,

Expected to ba reaülly blodegradable.

Bloaccumulation 5 Hs the potenllei to bloëceumulate,

Other Adverse Effects + in view oftthé high rate of loss from solution, the product is unilkety to pose a significant hazard io aquatte life.

13. DISPOSAL GONSIDERATIONS

Matertel Diéposet

the matorial generated to deterininé thé proper

wasle cléssification änd disposal methods in compliance with

applicable regutations.

Bo not dispose into ths environment, in drains or 1e water

57 Print Date 20.06.2007 MSDS_ZA. Shel|Sot 2325 D Shell Chemicals Version 3.4

Efféctive Date 16.02.2007

Material Safety Data Sheet accoïding to EC directive 2001/68EC

courses. Wäste product should not bé éllowed to conteminate

soil or Water.

Container Disposal + Drafn containér thoroughly. After diaining, vent În a safe place away from sparks and fire, Refar to Section 7 before handing

the product or containers. Résidues may cause an explosion

hazard If heated above the flash point. Do not punoture, cut or.

weld uncieaned drurns. Send to drum recoverer er metal

reclalmer.

Local Legislation : Disposa! should be in accordance with applicable regional, natlonal, and locallaws and regulations, Local regulations may

be morë stringent than regional or national requirements end

must be compiied with.

14. TRANSPORT INFORMATION

ADR

This material is nôt classified as dangerous under ADR regulations.

RID

This materiel fs not classified as: dangerous under RID regulations,

IMDG

This material ls not classified as dangérous under IMDGregutations.

IATA (Country variations may apply}

This material ls not classified as dangerous under IATA regulaëlons.

Adälfional Informatiôn *_ Packaging änd Transportation of Dangerous Goods is in compliance with Chapter VIT of the Regulations In terms of

the National Road Traffic Act of 1996, This regulation ts

supportéd by SABS codes of practicé SABS 0229 -

Packaging of DG for Road Traisport, SABS 0233 -1BC for

PDG and SABS 0282 Parts 1 & 3 - Emergency Response,

45. REGULATORY INFORMATION

The regutatory Information ls not intended to be comprehensive. Olher regulätions may apply to this material.

EC Label Name + KEROSINE (PETROLEUM), HYDRODESULFURIZED EC label'EC Number : 265-1849

EC Annex ! Number : 648-423-00-B,

EC Symbols 5 An Herrfui,

EC. Risk Phrases 3 :

EC Saïety Phrases

M SEAT

advice immediately {show the label where possible).

AICS 2: Listed,

DSL. : Listed,

6ft

Pânt Date 20.06.2007 MSDS_ZA(7) Shell Chemicols

Materlal Safety Data Sheet

INV {CN} TSCA

EINECS KECI (KR)

PIGGS (PH)

National Legislation

OE_HPV

Oihér infoniation

ShelSo! 2325

Veision 3,1

Effective Dale 16.02.2007

according to EC direclive 2001/58/EC

Listed,

Listed,

Listed, 265-185-4

Listad. KE-25620

Listed.

Listed.

In coripliance with the Occupational Health and. Safety Act 85

071988 and sallsfing the requirements of Regulation GN1178

belng the Hazardous Chemicals Subsatnce Regulation.

Amblent Air Quality Regulation (New)

16. OTHER INFORMATION

Rephrase(s)

RES Harmiul: Mey cause fung damage if swallowed,

R66 Repested exposure may cause skin drynéss or cracking.

MSDS Version Number

MSDS Effective Date

MSDS Revisions

MSDS Regulation

Uses and Restrictions 1

MSDS Distribution

Disclaimer

341

16.92.2007

À vertical bar (|} in the left margin Indicates an amendment

rom the previous version.

The content and format oFfhis safety dats shect ls In

accordance with Commission Ofrective 2001/58/EC of 27 July

2007, aménding for the second time Camsnisslon Directive

91/18B/EEC,

Industrial Solvent.

The information In this document should be made avalabte to

al who may handle the praduct

This information te based on our current knowledge and is

inténitfed to desoribe the product for the purposes of health,

safety and environmental requirements aniy, it should not

therefore be constried as guaranteeing any specific property

ofthe product,

Print Date 20.06.2007

7

MSDS_ZA